有機化学のブログ:面白い最新論文解説したり、有名反応をまとめたり、入門向け記事書いたり。

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  2023/01/05

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1. 文系でも3時間でわかる 超有機化学入門 研究者120年の熱狂
裳華房、諸藤 達也
本の紹介記事はこちら!ぜひ買ってください~!

原著論文

21.  Streptocyanine as an activation mode of amine catalysis for the conversion of pyridine rings to benzene rings
Morofuji, T.: Nagai, S.; Watanabe, A.; Inagawa, K.; Kano, N.
Chem. Sci. 2022, asap, (https://doi.org/10.1039/D2SC06225A)
解説記事はこちら
Selected as the front cover!

20. Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions
Morofuji, T.; Kurokawa, T.; Chitose, Y.; Adachi, C.; Kano, N.
Org. Biomol. Chem. 2022, 20, 9600-9603. (https://doi.org/10.1039/D2OB02055F)
解説記事はこちら

19. Thermal release of quinoliniums and simple alkenes from their photocycloadducts by a retro-Diels–Alder reaction
Morofuji, T.; Nagai, S.; Kano, N.
Tetrahedron 2022, 104, 154011. (doi.org/10.1016/j.tetlet.2022.154011)

18. Transition-Metal-Free O-Arylation of Alcohols and Phenols with S-Arylphenothiaziniums
Yoshida, T.; Honda, Y.; Morofuji, T.; Kano, N.
J. Org. Chem. 2022, 87, 7565–7573. (doi.org/10.1021/acs.joc.2c00771)
This paper is one of the most read articles of J. Org. Chem.

17. N-Methylphenothiazine S-Oxide Enabled Oxidative C(sp2)–C(sp2) Coupling of Boronic Acids with Organolithiums via Phenothiaziniums
Yoshida, T.; Honda, Y.; Morofuji, T.; Kano, N.
Org. Lett. 2021, 23, 9664-9668. (doi.org/10.1021/acs.orglett.1c03986)
This paper is one of the most read articles of Org. Lett.
解説記事はこちら

16. Synthesis and structure of a phosphinoboronic ester in a fused bicyclic framework
Kano, N.; O’Brien, N. J.;  Aoki, K.; Matsuda, Y.; Morofuji, T.
Dalton Trans. 2021, 50, 16003-16012. (doi.org/10.1039/D1DT02646A)

15. Protonation-Enhanced Reactivity of Triplet State in Dearomative Photocycloaddition of Quinolines to Olefins
Morofuji, T.; Nagai, S.; Chitose, Y.; Abe, M.; Kano, N.
Org. Lett. 2021, 23, 6257–6261. (doi.org/10.1021/acs.orglett.1c02026)
解説記事はこちら

14. Sequential Ring-Opening and Ring-Closing Reactions for Converting para-Substituted Pyridines into meta-Substituted Anilines
Morofuji, T.; Inagawa, K.; Kano, N.
Org. Lett. 202123, 6126–6130. (doi.org/10.1021/acs.orglett.1c02225)
解説記事はこちら
This paper is one of the most read articles of Org. Lett. in August.

13. Photocatalytic Giese-type reaction with alkylsilicates bearing C,O-bidentate ligands
Morofuji, T.; Matsui, Y.; Ohno, M.; Ikarashi, G.; Kano, N.
Chem. Eur. J2021, 27, 6713-6718.
解説記事はこちら

Selected as a cover feature! (https://doi.org/10.1002/chem.202100364)

12. Arylation of aryllithiums with S-arylphenothiazinium ions for biaryl synthesis
Morofuji, T.; Yoshida, T.; Tsutsumi, R.; Yamanaka, M.; Kano, N.
Chem. Commun. 2020, 56, 13995-13998.
オープンアクセス:どなたでもご覧いただけます!
解説記事はこちら

11. Terminal-oxidant-free photocatalytic C–H alkylations of heteroarenes with alkylsilicates as alkyl radical precursors
Ikarashi, G.; Morofuji, T.; Kano, N.
Chem. Commun. 2020, 56, 10006-10009.
オープンアクセス:どなたでもご覧いただけます!
解説記事はこちら

10. Photocatalytic C–H Amination of Aromatics Overcoming Redox Potential Limitations
Morofuji, T.; Ikarashi, G.; Kano, N.
Org. Lett. 2020, 22, 2822-2827.
This paper is one of the most read articles of Org. Lett. in April, 2020.
解説記事はこちら

9. Connecting a carbonyl and a p-conjugated group through a p-phenylene linker by (5+1) benzene ring formation
Morofuji, T.; Kinoshita, H.; Kano, N.
Chem. Commun. 2019, 55, 8575-8578.
オープンアクセス:どなたでもご覧いただけます!(論文PDF→carbonyl-p-phenylene-pai)
解説記事はこちら

8. Heterocyclization Approach for Electrooxidative Coupling of Functional Primary Alkylamines with Aromatics
Morofuji, T.; Shimizu, A.; Yoshida, J.
J. Am. Chem. Soc. 2015, 137, 9816-9819. 
Highlighted in J. Am. Chem. Soc.

7. Electrochemical Intramolecular C–H Amination: Synthesis of Benzoxazoles and Benzothiazoles
Morofuji, T.; Shimizu, A.; Yoshida, J.
Chem. Eur. J. 2015, 21, 3211-3214.

6. Direct C–N Coupling of Imidazoles with Aromatic and Benzylic compounds via Electrooxidative C–H Functionalization
Morofuji, T.; Shimizu, A.; Yoshida, J.
J. Am. Chem. Soc. 2014, 136, 4496-4499. 
Highlighted in J. Am. Chem. Soc.
解説記事はこちら

5. Redox Active Dendronized Polystyrenes Equipped with Peripheral Triarylamines
Nokami, T.; Musya, N.; Morofuji, T.; Takeda, K.; Takumi, M.; Shimizu, A.; Yoshida, J.
Beilstein J. Org. Chem. 2014, 10, 3079-3103.

4. Electrochemical C–H Amination: Synthesis of Aromatic Primary Amines via N-Arylpyridinium Ions
Morofuji, T.; Shimizu, A.; Yoshida, J.
J. Am. Chem. Soc. 2013, 135, 5000-5003. 
Highlighted in Angew. Chem. Int. Ed.
解説記事はこちら

3. Metal-and Chemical-Oxidant-Free C–H/C–H Cross-Coupling of Aromatic Compounds: The Use of Radical-cation Pools
Morofuji, T.; Shimizu, A.; Yoshida, J.
Angew. Chem., Int. Ed. 2012, 51, 7259-7262.

2. Electrochemical Synthesis of Dendritic Diarylcarbenium Ion Pools
Nokami, T.; Watanabe, T.; Musya, N.; Suehiro, T.; Morofuji, T.; Yoshida, J.
Tetrahedron 2011, 67, 4664-4671.

1. Direct Dendronization of Polystyrenes Using Dendritic Diarylcarbenium Ion Pools
Nokami, T.;Watanabe, T.; Musya, N.; Morofuji, T.; Tahara, K.; Tobe, Y.; Yoshida, J.
Chem. Commun. 2011, 47, 5575-5577.

 

総説

2. Recent Progress in C(sp2)–C(sp2) Bond Formation Using Ligand Coupling on Sulfur(IV)
Morofuji, T.; Kano, N.
Synthesis 2022, 54, 5186-5191.

1. Reaction Integration Using Electrogenerated Cationic Intermediates
Yoshida, J.; Shimizu, A.; Ashikari, Y.; Morofuji, T.; Hayashi, R.; Nokami, T.; Nagaki, A.
Bull. Chem. Soc. Jpn. 2015, 88, 763-775.

 

その他

3. クロスウルマンカップリングの驚異的進展  似た者どうしをくっつけろ, 現代化学2019年11月号
諸藤達也

2. 有機触媒でホウ素が芳香環から芳香環へ移動する!, 現代化学2019年10月号
諸藤達也

1. 求核性のある金錯体, 月刊化学2019年6月号(PDF)
諸藤 達也

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